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Chapter 20: Organic Chemistry

20.4: Reactions of Organic Compounds

Types of Organic Reactions

Substitution Reaction
A reaction in which one atom or group in a molecule is replaced by another atom or group.
Addition Reaction
A reaction in which atoms are added to a double or triple bond, converting it to a single bond.
Elimination Reaction
A reaction in which a small molecule (e.g., water or hydrogen halide) is removed, forming a double or triple bond.
Oxidation Reaction
A reaction in which a molecule loses electrons or hydrogen atoms and gains oxygen atoms.
Reduction Reaction
A reaction in which a molecule gains electrons or hydrogen atoms and loses oxygen atoms.
Polymerization Reaction
A reaction in which small molecules (monomers) combine to form a larger molecule (polymer).

Reaction Mechanisms

  • Nucleophilic Substitution: A nucleophile replaces a leaving group in a molecule.
  • Electrophilic Addition: An electrophile attacks a double or triple bond, forming a single bond.
  • Free Radical Substitution: Involves free radicals as intermediates, common in halogenation reactions.

Factors Affecting Organic Reactions

  • Reactivity: Determined by the functional groups and bonds in the molecule.
  • Temperature: Higher temperatures can increase reaction rates.
  • Catalysts: Substances that speed up reactions without being consumed.
  • Solvent Effects: Polar and nonpolar solvents can influence reaction mechanisms and rates.

Applications of Organic Reactions

  • Production of plastics through polymerization reactions.
  • Synthesis of pharmaceuticals via substitution and addition reactions.
  • Creation of fuels and lubricants through cracking and reforming processes.
  • Development of dyes and pigments using complex organic reactions.

Questions for Students

  1. Define the following reactions: substitution, addition, and elimination.
  2. What is the difference between oxidation and reduction reactions?
  3. Describe the role of catalysts in organic reactions.
  4. What are the applications of polymerization reactions in everyday life?
  5. Explain how reaction mechanisms like nucleophilic substitution work.